Facile synthesis of scheelite‑type NdOsO4 directly grown on carbon cloth for oxygen evolution reaction
Abstract
In the recent work, the scheelite-type ABO4
compound (A = Nd and B = Os) is synthesized via a hydrothermal route directly
grown on carbon cloth (
NdOsO4/CC). The as-obtained electrocatalysts are analyzed by X-ray diffraction (XRD), scanning
electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDXS), and Brunauer–Emmett–Teller (BET) to confirm
the elemental, structural, morphological, and textural properties, respectively. The scheelite-type materials can easily regulate
the oxygen evolution reaction (OER) owing to the presence of oxygen vacancy and high conductivity. Therefore, the fabricated
material is employed for electrochemical studies utilizing electrochemical impedance spectroscopy (EIS), CV polarization curves,
linear sweep voltammetry (LSV), and chronoamperometry (CA) in an alkaline medium and responds to low overpotential of
238.0 mV and small Tafel slope of 85.0 mV dec−
1 with the enduring stability of 20 h. In the current study, oxygen-deficient
scheelite-type perovskites, such as ABO4,
appear to represent a novel class of high-performance electrocatalyst for processes
involving active oxygen intermediates, like OER and oxygen reduction reaction (ORR) in future applications.