Thickness controlling bandgap energy, refractive index and electrical conduction mechanism of 2D Tungsten Diselenide (WSe2) thin films for photovoltaic applications

This paper reports thickness-dependent structural, morphological, optical, and electrical conduction mechanism of room temperature electron beam evaporated 2D WSe2 thin films on glass substrate. The thickness of the WSe2 films was varied from 100 to 400 nm. XRD results showed the fact that the WSe2 films are crystallized in a hexagonal structure. The nanostructure nature is verified from morphological studies. It was found that the microstrain decreases, while the crystallite size rises as the thickness of WSe2 film increases. The thickness-dependent optical constants and energy bandgap was studied using spectroscopic ellipsometry (SE). The refractive index and extinction coefficient dispersion curves of WSe2 film with various thicknesses display two strong absorption peaks A and B below 800 nm at 580 nm and 770 nm, which are belong to excitonic absorption features. Further, the results illustrate …